Einstein

Read Einstein for Free Online

Book: Read Einstein for Free Online
Authors: Walter Isaacson
gas.”
    He did a calculation using Boltzmann’s statistical formulas for entropy. The statistical mechanics that described a dilute gas of particles was mathematically the same as that for blackbody radiation. This led Einstein to declare that the radiation “behaves thermodynamically as if it consisted of mutually independent energy quanta.” It also provided a way to calculate the energy of a “particle” of light at a particular frequency, which turned out to be in accord with what Planck had found. 17
    Einstein went on to show how the existence of these light quanta could explain what he graciously called Lenard’s “pioneering work” onthe photoelectric effect. If light came in discrete quanta, then the energy of each one was determined simply by the frequency of the light multiplied by Planck’s constant. If we assume, Einstein suggested, “that a light quantum transfers its entire energy to a single electron,” then it follows that light of a higher frequency would cause the electrons to emit with more energy. On the other hand, increasing the intensity of the light (but not the frequency) would simply mean that more electrons would be emitted, but the energy of each would be the same.
    That was precisely what Lenard had found. With a trace of humility or tentativeness, along with a desire to show that his conclusions had been deduced theoretically rather than induced entirely from experimental data, Einstein declared of his paper’s premise that light consists of tiny quanta: “As far as I can see, our conception does not conflict with the properties of the photoelectric effect observed by Mr. Lenard.”
    By blowing on Planck’s embers, Einstein had turned them into a flame that would consume classical physics. What precisely did Einstein produce that made his 1905 paper a discontinuous—one is tempted to say quantum—leap beyond the work of Planck?
    In effect, as Einstein noted in a paper the following year, his role was that he figured out the physical significance of what Planck had discovered. 18 For Planck, a reluctant revolutionary, the quantum was a mathematical contrivance that explained how energy was emitted and absorbed when it interacted with matter. But he did not see that it related to a physical reality that was inherent in the nature of light and the electromagnetic field itself. “One can interpret Planck’s 1900 paper to mean only that the quantum hypothesis is used as a
mathematical
convenience introduced in order to calculate a statistical distribution, not as a new
physical
assumption,” write science historians Gerald Holton and Steven Brush. 19
    Einstein, on the other hand, considered the light quantum to be a feature of reality: a perplexing, pesky, mysterious, and sometimes maddening quirk in the cosmos. For him, these quanta of energy (which in 1926 were named photons) 20 existed even when light was moving through a vacuum. “We wish to show that Mr. Planck’s determinationof the elementary quanta is to some extent independent of his theory of blackbody radiation,” he wrote. In other words, Einstein argued that the particulate nature of light was a property of the light itself and not just some description of how the light interacts with matter. 21
    Even after Einstein published his paper, Planck did not accept his leap. Two years later, Planck warned the young patent clerk that he had gone too far, and that quanta described a process that occurred during emission or absorption, rather than some real property of radiation in a vacuum. “I do not seek the meaning of the ‘quantum of action’ (light quantum) in the vacuum but at the site of absorption and emission,” he advised. 22
    Planck’s resistance to believing that the light quanta had a physical reality persisted. Eight years after Einstein’s paper was published, Planck proposed him for a coveted seat in the Prussian Academy of Sciences. The letter he and other supporters wrote was filled with praise, but

Similar Books

The Roy Stories

Barry Gifford

The Calling

Barbara Steiner

Heaven's Fire

Patricia Ryan

Double Cross

Sigmund Brouwer

Feral

Holly Schindler