Einstein

Read Einstein for Free Online Page B

Book: Read Einstein for Free Online
Authors: Walter Isaacson
conditions later became known as Avogadro’s number. Determining it precisely was, and still is, rather difficult. A current estimate is approximately 6.02214 x 10 23 . (This is a big number: that many unpopped popcorn kernels when spread across the United States would cover the country nine miles deep.) 29
    Most previous measurements of molecules had been done by studying gases. But as Einstein noted in the first sentence of his paper, “The physical phenomena observed in liquids have thus far not served for the determination of molecular sizes.” In this dissertation (after a few math and data corrections were later made), Einstein was the first person able to get a respectable result using liquids.
    His method involved making use of data about viscosity, which is how much resistance a liquid offers to an object that tries to move through it. Tar and molasses, for example, are highly viscous. If you dissolve sugar in water, the solution’s viscosity increases as it gets more syrupy. Einstein envisioned the sugar molecules gradually diffusing their way through the smaller water molecules. He was able to come up with two equations, each containing the two unknown variables—the size of the sugar molecules and the number of them in the water—that he was trying to determine. He could then solve for these unknown variables. Doing so, he got a result for Avogadro’s number that was 2.1 x 10 23 .
    That, unfortunately, was not very close. When he submitted his paper to the
Annalen der Physik
in August, right after it had been accepted by Zurich University, the editor Paul Drude (who was blissfully unaware of Einstein’s earlier desire to ridicule him) held up its publication because he knew of some better data on the properties of sugar solutions. Using this new data, Einstein came up with a result that was closer to correct: 4.15 x 10 23 .
    A few years later, a French student tested the approach experimentally and discovered something amiss. So Einstein asked an assistant in Zurich to look at it all over again. He found a minor error, which when corrected produced a result of 6.56 x 10 23 , which ended up being quite respectable. 30
    Einstein later said, perhaps half-jokingly, that when he submitted his thesis, Professor Kleiner rejected it for being too short, so he added one more sentence and it was promptly accepted. There is no documentary evidence for this. 31 Either way, his thesis actually became one of his most cited and practically useful papers, with applications in such diverse fields as cement mixing, dairy production, and aerosol products. And even though it did not help him get an academic job, it did make it possible for him to become known, finally, as Dr. Einstein.
Brownian Motion, May 1905
     
    Eleven days after finishing his dissertation, Einstein produced another paper exploring evidence of things unseen. As he had been doing since 1901, he relied on statistical analysis of the random actions of invisible particles to show how they were reflected in the visible world.
    In doing so, Einstein explained a phenomenon, known as Brownian motion, that had been puzzling scientists for almost eighty years: why small particles suspended in a liquid such as water are observed to jiggle around. And as a byproduct, he pretty much settled once and for all that atoms and molecules actually existed as physical objects.
    Brownian motion was named after the Scottish botanist Robert Brown, who in 1828 had published detailed observations about how minuscule pollen particles suspended in water can be seen to wiggle and wander when examined under a strong microscope. The study was replicated with other particles, including filings from the Sphinx, and a variety of explanations was offered. Perhaps it had something to do with tiny water currents or the effect of light. But none of these theories proved plausible.
    With the rise in the 1870s of the kinetic theory, which used the random motions of molecules to explain things

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